Objective:
The purpose of this experiment is to measure the wavelength of a few visible light and form a linear transformation of the derived wavelength, and use this to measure the spectra of hydrogen atom and an unknown to find out what the unknown is.
Procedures:
1. Set up as instructed in the lab manual, put the light source as the white light.
2. Record the position for each light seen through the diffraction grating.
3. Change the light source to hydrogen atoms and unknowns and perform same procedure.
Results:
The acceptable visible light range is from 390 nm to 750 nm.
The wavelength is derived using formula:
L is 100 cm, and d is 1/500 mm.
For white light:
Color
Distance D (cm)
λ(nm)
Purple Begins
17.5
345
Purple ->
Blue
22
430
Blue ->
Green
24.5
478
Green ->
Yellow
26
503
Yellow ->
Red
28
539
Red
35
661
Red ends
40
743
Using 345 and 743 to do the linear transformation, the equation is λ = 0.905λ'+78 in nm.
Then for the hydrogen atom:
λ is derived from the early equation and linear transformation.
For the unknown, we derived following data:
Trial 1: | ||
Color | Distance D (cm) | λ(nm) |
Yellow | 29 | 582 |
Green | 27 | 550 |
Blue | 21 | 450 |
Trial 2: | ||
Color | Distance D (cm) | λ(nm) |
Yellow | 29.5 | 590 |
Green | 28 | 566 |
Blue | 21.5 | 458 |
We suspect the unknown to be Mercury (Hg). The spectra for Mercury is:
The spectra for Hg shows peak at 435, 545, and 580 nm, which is very close to the calculated data.
Discussion:
The measurement is very inaccurate for the precise distance from diffraction grating to the light source is hard to measure, so does the displacement. The derived spectra for white light gives a fairly precise linear transformation to the system. The unknown is Hg as what professor told us, but the wacelength for blue light is comparably different from the theoretical one.